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71.
The photoluminescence, dielectric relaxation, ferroelectric hysteresis, and field-induced strain properties of Pr3+-doped 0.24Pb(In1/2Nb1/2)O3-0.42Pb(Mg1/3Nb2/3)O3-0.34PbTiO3 (PIN-PMN-PT:Pr3+) multifunctional ceramics have been investigated. It was found that Pr3+ doping enhanced the dielectric diffuseness and relaxation behavior of PIN-PMN-PT ceramics. Slim P-E loops and S-E curves appear in PIN-PMN-PT:Pr3+ ceramics when the Pr3+ doping concentration reaches 1.4 mol%. Local domain configurations associated with phase transitions were investigated by piezoresponse force microscopy (PFM). Large electrostrictive coefficient Q33 (?0.03 m4/C2) and high energy-storage efficiency η (92%) were obtained in 2 mol% Pr3+-doped PIN-PMN-PT ceramic in the ergodic relaxor (ER) phase at room temperature. The giant electrostrictive effect and excellent energy-storage performance are related to the field-induced dynamic behavior of polar nanoregions (PNRs). The results show that the PIN-PMN-PT:Pr3+ system is an excellent multifunctional material for making electromechanical and energy storage devices.  相似文献   
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为适应社会发展的脚步,满足民众的实际需求,工程建设企业正不断寻求新型的建筑设计方案和施工方案,多层钢结构模块和钢框架复合建筑结构建设模式应用,以实际的工业园区建设为例,分析研究建筑多层钢结构模块与钢框架复合建筑结构的设计要求和具体施工技术应用方案,通过一系列数据研究和对比,分析多层钢结构模块与钢框架复合建筑结构技术要求的优势,可为相关工作者提供帮助.  相似文献   
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Benzothiophene (BT) is a key sulfur-containing intermediate product in the thermal conversion process of coal and heavy oil. The migration process of the sulfur element may affect the thermal utilization design of BT. In this paper, BT was used as a model compound to simulate the supercritical water gasification (SCWG) process by molecular dynamics with a reactive force field (ReaxFF) method, and the laws of hydrogen production and sulfur migration mechanisms were obtained. Increasing the molecule number of supercritical water (SCW) and increasing the reaction temperature can enhance the generation of hydrogen and promote the conversion of organic sulfur to inorganic sulfur. Water was the main source of H2, and H2S was the main gaseous sulfur-containing product. SCW had a certain degree of oxidation due to a large number of hydroxyl radicals, which could increase the valence of sulfur. The conversion process of BT in SCW was mainly divided into four stages, including thiophene ring-opening; sulfur separation or carbon chain broke with sulfur retention; carbon chain cleaved, and gas generation. The lumped kinetic parameters of the conversion of sulfur in BT to inorganic sulfur were calculated, and the activation energy was 369.98 kJ/mol, which was much lower than those under pyrolysis conditions. This article aims to clarify the synergistic characteristics of hydrogen production and sulfur migration in the SCWG process of BT from the molecular perspective, which is expected to provide a theoretical basis for pollutant directional removal during hydrogen production by sulfur-containing organic matters in SCW.  相似文献   
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The nickel-carbon nanofibers (Ni-C NFs) were fabricated by the electrospinning of poly(vinyl alcohol) (PVA) and nickel acetate tetrahydrate (NiAc) solution precursor with succedent PVA pyrolyzation and calcination process. The microwave absorption performance and electromagnetic (EM) parameters of the NFs were researched over the frequency range of 2.0–18.0?GHz. Both the impedance matching and EM wave absorption properties of the Ni-C NFs were improved by changing the carbonization temperature. The effect of graphitization degree on reflection loss (RL) and the possible loss mechanisms were directly displayed in the comparative study of each sample. The optimal RL value of ??44.9?dB and an effective frequency bandwidth of 3.0?GHz under a thickness of 3.0?mm can be reached by a sample calcined at 650?°C. These lightweight Ni-C NFs composites can be promising candidates for EM wave absorbers due to the combination of multiple loss mechanisms, nano-size effect and good impedance matching between Ni nanoparticles and CNFs.  相似文献   
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Reducing the Platinum (Pt) loading while maintaining the performance is highly desired for promoting the commercial use of proton exchange membrane fuel cells (PEMFCs). Different methods have been adopted to fabricate catalyst layers (CLs) with low Pt loading, including utilizing lower Pt/C catalysts (MA), mixing high Pt/C catalysts with bare carbon black particles (MB), and reducing CL thickness while maintaining high Pt/C ratio (MC). In this study, self-developed pore-scale model is adopted to investigate the performance of the three Pt reduction methods. It is found that MA shows the best performance while MB shows the worst. Then, effects of Pt dispersion are further explored. The results show that denser Pt sites will result in higher local oxygen flux and thus higher local transport resistance. Therefore, MA method, which shows the better Pt dispersion, leads to improved performance. Third, CLs with quasi-realistic structures are investigated. Higher tortuosity resulting from the random pores produces higher bulk resistance along the thickness direction, while MA still exhibits the best performance. Finally, improved CL structures are investigated by designing perforated CL structures. It is found that adding perforations can significantly reduce the bulk transport resistance and can improve the CL performance. It is demonstrated that CL structure plays important roles on performance, and there are still huge potentials to further improve CL performance by increasing Pt dispersion and optimizing CL structures.  相似文献   
80.
Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO3 (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO3 at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO3 in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains.  相似文献   
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